Metal-organic framework-based nanomaterials for CO₂ storage: A review

• Ha Huu Do,
• Iqra Rabani and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 964–970, doi:10.3762/bjnano.14.79

• -organic frameworks (MOFs) promising contenders for CO2 uptake. This review commences by discussing recent advancements in MOFs with diverse adsorption sites, encompassing open metal sites and Lewis basic centers. Next, diverse strategies aimed at enhancing CO2 adsorption capabilities are presented

• ]. Therefore, identification and development of durable and efficient adsorbents are critical to the successful implementation of CCS. Until now, various classes of materials have been investigated for CO2 adsorption, such as covalent organic frameworks, molecular sieves, activated carbon, and metal-organic

• frameworks (MOFs) [11][12][13]. Notably, MOFs constructed from metal ions and organic linkers are expected to be alternative materials to the organic alcohol amines in CCS [14]. These nanosized materials posess unique properties such as ultrahigh surface area, tunable pore size, open metal sites (OMSs), and

Ni, Co, Zn, and Cu metal-organic framework-based nanomaterials for electrochemical reduction of CO₂: A review

• Ha Huu Do and
• Hai Bang Truong

Beilstein J. Nanotechnol. 2023, 14, 904–911, doi:10.3762/bjnano.14.74

• of converting CO2 into valuable chemicals through electrochemical techniques has garnered significant attention. Metal-organic frameworks (MOFs) have occured as highly prospective materials for the reduction of CO2, owing to their exceptional attributes including extensive surface area, customizable

• exhibited considerable variation depending on the elemental composition of pure metal catalysts [19]. Notably, Au, Ag, and Zn catalysts exhibit preferential CO generation, while Sn, In, and Pb catalysts prove effective in producing formate ions (HCOO−) [20]. Metal-organic frameworks (MOFs) are established

Metal-organic framework-based nanomaterials as opto-electrochemical sensors for the detection of antibiotics and hormones: A review

• Akeem Adeyemi Oladipo,
• Saba Derakhshan Oskouei and
• Mustafa Gazi

Beilstein J. Nanotechnol. 2023, 14, 631–673, doi:10.3762/bjnano.14.52

• that are time-consuming and require experienced professionals. Metal-organic frameworks (MOFs) with variable porosity, active functional sites, and fluorescence capacity are attractive materials for developing opto-electrochemical sensors. Herein, the insights into the capabilities of electrochemical

• demonstrated a wide linearity range for the detection of the antibiotic. Metal-organic frameworks: properties and synthesis In recent years, there has been a lot of interest in metal-organic frameworks (MOFs) [72][73][74][75], which are extremely porous materials. They are highly crystalline materials with

Cyclodextrins as eminent constituents in nanoarchitectonics for drug delivery systems

• Makoto Komiyama

Beilstein J. Nanotechnol. 2023, 14, 218–232, doi:10.3762/bjnano.14.21

• ]. Metal complexes of CyD [93] and metal-organic frameworks (MOFs) containing CyDs [94][95][96] were also developed for DDSs. By combining a thermoresponsive poly(N-isopropylacrylamide) star polymer with a β-CyD core, adamantane-terminated poly(ethylene glycol) polymer, and α-CyD, a supramolecular hydrogel

Design of surface nanostructures for chirality sensing based on quartz crystal microbalance

• Yinglin Ma,
• Xiangyun Xiao and
• Qingmin Ji

Beilstein J. Nanotechnol. 2022, 13, 1201–1219, doi:10.3762/bjnano.13.100

• volatile organic compounds (VOCs) with a remarkable degree of selectivity, which may promote the development of electronic nose systems for chiral analytes. Metal–organic frameworks. Metal–organic frameworks (MOFs) are unique porous crystalline materials fabricated by the self-assembly of metal ions or

Spindle-like MIL101(Fe) decorated with Bi₂O₃ nanoparticles for enhanced degradation of chlortetracycline under visible-light irradiation

• Chen-chen Hao,
• Fang-yan Chen,
• Kun Bian,
• Yu-bin Tang and
• Wei-long Shi

Beilstein J. Nanotechnol. 2022, 13, 1038–1050, doi:10.3762/bjnano.13.91

• China 10.3762/bjnano.13.91 Abstract Improving the photocatalytic performance of metal–organic frameworks (MOFs) is an important way to expand its potential applications. In this work, zero-dimensional (0D) Bi2O3 nanoparticles were anchored to the surface of tridimensional (3D) MIL101(Fe) by a facile

• efficient photocatalysts for CTC degradation. Metal–organic frameworks (MOFs) are a kind of micro- or mesoporous materials established by the self-assembly of organic linkers and metal-cluster or metal-ion nodes [19]. The MOF materials possess large surface areas, high pore volume, tunability, uniform

The role of sulfonate groups and hydrogen bonding in the proton conductivity of two coordination networks

• Ali Javed,
• Felix Steinke,
• Stephan Wöhlbrandt,
• Hana Bunzen,
• Norbert Stock and
• Michael Tiemann

Beilstein J. Nanotechnol. 2022, 13, 437–443, doi:10.3762/bjnano.13.36

• coordination polymers (CPs), such as (porous) metal-organic frameworks (MOFs) and (non-porous, yet cross-linked) coordination networks [12], may offer alternatives to Nafion because of their structural controllability and high crystallinity [13]. The quest to develop new proton-conducting network materials is

Interfacial nanoarchitectonics for ZIF-8 membranes with enhanced gas separation

• Season S. Chen,
• Zhen-Jie Yang,
• Chia-Hao Chang,
• Hoong-Uei Koh,
• Sameerah I. Al-Saeedi,
• Kuo-Lun Tung and
• Kevin C.-W. Wu

Beilstein J. Nanotechnol. 2022, 13, 313–324, doi:10.3762/bjnano.13.26

• rise to specific molecule-sized pores, which yield a high separation factor in the separation processes [9][10][11][12]. Wider application of zeolite membranes in separation is limited by the narrow pore-size range (0.2–2 nm) and the difficult chemical modification. Metal-organic frameworks (MOFs) are

Recent progress in magnetic applications for micro- and nanorobots

• Ke Xu,
• Shuang Xu and
• Fanan Wei

Beilstein J. Nanotechnol. 2021, 12, 744–755, doi:10.3762/bjnano.12.58

• ). Nayak [39] used metal-organic frameworks (MOFs) to adsorb heavy metals in water for water purification. MOFs have a very high specific surface area and modular structure, showing great advantages in the sustainable supply of clean drinking water. Later, Yu et al. [40] reported a method to disassemble

High-performance asymmetric supercapacitor made of NiMoO₄ nanorods@Co₃O₄ on a cellulose-based carbon aerogel

• Meixia Wang,
• Jing Zhang,
• Xibin Yi,
• Benxue Liu,
• Xinfu Zhao and
• Xiaochan Liu

Beilstein J. Nanotechnol. 2020, 11, 240–251, doi:10.3762/bjnano.11.18

• a capacitance retention of 84.1% after 2000 cycles [23]. Metal-organic frameworks (MOFs) with high porosity and tunable functionality are ideal sacrificial templates to synthesize metal oxides [24][25][26]. As a MOF derivative, Co3O4 derived from the zeolitic imidazolate framework-67 (ZIF-67) is

Air oxidation of sulfur mustard gas simulants using a pyrene-based metal–organic framework photocatalyst

• Ghada Ayoub,
• Mihails Arhangelskis,
• Xuan Zhang,
• Florencia Son,
• Timur Islamoglu,
• Tomislav Friščić and
• Omar K. Farha

Beilstein J. Nanotechnol. 2019, 10, 2422–2427, doi:10.3762/bjnano.10.232

• selection of solvent choices since solubility of the chromophore does not need to be considered, and lower probability of photobleaching [24][25]. Metal–organic frameworks (MOFs), porous crystalline materials comprised of metal nodes and organic linkers, have attracted tremendous attention in heterogeneous

Synthesis of highly active ETS-10-based titanosilicate for heterogeneously catalyzed transesterification of triglycerides

• Muhammad A. Zaheer,
• David Poppitz,
• Khavar Feyzullayeva,
• Marianne Wenzel,
• Jörg Matysik,
• Radomir Ljupkovic,
• Aleksandra Zarubica,
• Alexander A. Karavaev,
• Andreas Pöppl,
• Roger Gläser and
• Muslim Dvoyashkin

Beilstein J. Nanotechnol. 2019, 10, 2039–2061, doi:10.3762/bjnano.10.200

• removal [13]. Amongst the prospective solid catalysts designed for transesterification reactions, such as calcium [14] and other metal oxides [15], metal–organic frameworks (MOFs) [10], silica-supported catalysts [16], biochar [17] and other biomass-derived catalysts [18], zeolites and molecular sieves

Nanostructured and oriented metal–organic framework films enabling extreme surface wetting properties

• Andre Mähringer,
• Julian M. Rotter and
• Dana D. Medina

Beilstein J. Nanotechnol. 2019, 10, 1994–2003, doi:10.3762/bjnano.10.196

• . Keywords: antifog; antifouling; biomimetic coatings; metal–organic frameworks (MOFs); superhydrophilic; superoleophobic; thin films; vapor-assisted conversion; Introduction Over millions of years, plants and animals have evolved a spectrum of surface designs enabling specific wetting properties tailored

• development of a straightforward and versatile bottom-up synthesis scheme enabling tunable surface morphologies for controlled wetting properties is still challenging and highly desired. Metal–organic frameworks (MOFs) are porous, crystalline materials featuring a great structural and chemical diversity [40

Charge-transfer interactions between fullerenes and a mesoporous tetrathiafulvalene-based metal–organic framework

• Manuel Souto,
• Joaquín Calbo,
• Samuel Mañas-Valero,
• Aron Walsh and
• Guillermo Mínguez Espallargas

Beilstein J. Nanotechnol. 2019, 10, 1883–1893, doi:10.3762/bjnano.10.183

• /bjnano.10.183 Abstract The design of metal–organic frameworks (MOFs) incorporating electroactive guest molecules in the pores has become a subject of great interest in order to obtain additional electrical functionalities within the framework while maintaining porosity. Understanding the charge-transfer

• increased by two orders of magnitude due to the CT interactions between C60 and the TTF-based framework. Keywords: charge transfer; donor–acceptor; fullerene; metal–organic frameworks (MOFs); tetrathiafulvalene (TTF); Introduction Metal–organic frameworks (MOFs), which are crystalline porous materials

• C60 and discrete π-extended TTF molecules have been extensively studied in solution during the last years [42][43][44][45][46][47]. In contrast, much less is known about their supramolecular interactions in solid-state polymeric structures such as metal–organic frameworks. MOFs using TTF as ligands

Long-term entrapment and temperature-controlled-release of SF₆ gas in metal–organic frameworks (MOFs)

• Hana Bunzen,
• Andreas Kalytta-Mewes,
• Leo van Wüllen and
• Dirk Volkmer

Beilstein J. Nanotechnol. 2019, 10, 1851–1859, doi:10.3762/bjnano.10.180

• frameworks (MOFs); sulfur hexafluoride; Introduction Metal–organic frameworks (MOFs) are coordination polymers with organic ligands containing (potential) voids [1]. Their porosity and high surface area make them attractive materials for adsorption-based applications [2][3][4][5]. MOFs have been suggested

• temperature, vacuum and acid-induced framework decomposition was also investigated. The controlled gas release using elevated temperature has the additional benefit that the host MOF can be reused for further gas capture cycles. Keywords: benzobistriazole; gas storage; kinetic trapping; metal–organic

The impact of crystal size and temperature on the adsorption-induced flexibility of the Zr-based metal–organic framework DUT-98

• Simon Krause,
• Volodymyr Bon,
• Hongchu Du,
• Rafal E. Dunin-Borkowski,
• Ulrich Stoeck,
• Irena Senkovska and
• Stefan Kaskel

Beilstein J. Nanotechnol. 2019, 10, 1737–1744, doi:10.3762/bjnano.10.169

• applications. This work thus extends the limited amount of studies on crystal size effects in flexible MOFs and hopefully motivates further investigations in this field. Keywords: crystal engineering; crystal size; flexible metal–organic frameworks; MOFs; water adsorption; Introduction In the past 20 years

• , research in the area of metal–organic frameworks (MOFs) has delivered various record-holding materials in terms of surface area [1] and gas storage [2] and has also given rise to unprecedented adsorption phenomena [3] often associated with structural transitions. An increasing number of the so-called

Materials nanoarchitectonics at two-dimensional liquid interfaces

• Katsuhiko Ariga,
• Michio Matsumoto,
• Taizo Mori and
• Lok Kumar Shrestha

Beilstein J. Nanotechnol. 2019, 10, 1559–1587, doi:10.3762/bjnano.10.153

• well as two-dimensional molecular patterning, are briefly explained. In the following sections, several topics of materials nanoarchitectonics at liquid interfaces such as the preparation of two-dimensional metal-organic frameworks (MOFs) and covalent organic frameworks (COFs), the fabrication of multi

• synthesize two-dimensional materials. The recent developments of synthetic two-dimensional crystalline polymers (2DCPs), such as two-dimensional metal-organic frameworks (MOFs) and two-dimensional covalent organic frameworks (COFs), have unveiled their intriguing chemistry and properties, and have shown

A highly efficient porous rod-like Ce-doped ZnO photocatalyst for the degradation of dye contaminants in water

• Binjing Hu,
• Qiang Sun,
• Chengyi Zuo,
• Yunxin Pei,
• Siwei Yang,
• Hui Zheng and
• Fangming Liu

Beilstein J. Nanotechnol. 2019, 10, 1157–1165, doi:10.3762/bjnano.10.115

• ]. In recent years, metal organic frameworks (MOFs) have been intensively investigated and widely utilized in various fields, such as electrocatalysis [14], heterogeneous catalysis [15] and photocatalysis [16]. Yang et al. [17] reported that Ga-MOF displayed moderate to high catalytic activity of

Ultrathin hydrophobic films based on the metal organic framework UiO-66-COOH(Zr)

• Miguel A. Andrés,
• Clemence Sicard,
• Christian Serre,
• Olivier Roubeau and
• Ignacio Gascón

Beilstein J. Nanotechnol. 2019, 10, 654–665, doi:10.3762/bjnano.10.65

• . Keywords: hydrophobic coating; Langmuir–Blodgett (LB) films; metal organic framework (MOF); surface modification; UiO-66-COOH(Zr); Introduction Metal organic frameworks (MOFs) are well-known, crystalline, porous materials formed by metal ions (or metallic clusters) and organic ligands coordinated in a pre

One-step nonhydrolytic sol–gel synthesis of mesoporous TiO₂ phosphonate hybrid materials

• Yanhui Wang,
• P. Hubert Mutin and
• Johan G. Alauzun

Beilstein J. Nanotechnol. 2019, 10, 356–362, doi:10.3762/bjnano.10.35

• lack of porosity of this sample likely results from the interdigitation or mixing of the alkyl chains. These mesoporous metal oxide–phosphonate materials can be seen as a low-cost alternative to periodic mesoporous organosilicas (PMOs) and metal–organic frameworks (MOFs) for applications in the field

The nanoscaled metal-organic framework ICR-2 as a carrier of porphyrins for photodynamic therapy

• Jan Hynek,
• Sebastian Jurík,
• Martina Koncošová,
• Jaroslav Zelenka,
• Ivana Křížová,
• Tomáš Ruml,
• Kaplan Kirakci,
• Ivo Jakubec,
• František Kovanda,
• Kamil Lang and
• Jan Demel

Beilstein J. Nanotechnol. 2018, 9, 2960–2967, doi:10.3762/bjnano.9.275

• Technology, Technická 5, 166 28 Prague, Czech Republic 10.3762/bjnano.9.275 Abstract Nanosized porphyrin-containing metal-organic frameworks (MOFs) attract considerable attention as solid-state photosensitizers for biological applications. In this study, we have for the first time synthesised and

• ; Introduction Metal-organic frameworks (MOFs) are a class of crystalline coordination polymers possessing potential voids. Their structures combine inorganic nodes, metal centres forming so-called secondary building units (SBU), with organic linkers. The diversity of possible SBUs coupled with organic linkers

Uniform cobalt nanoparticles embedded in hexagonal mesoporous nanoplates as a magnetically separable, recyclable adsorbent

• Can Zhao,
• Yuexiao Song,
• Tianyu Xiang,
• Wenxiu Qu,
• Shuo Lou,
• Xiaohong Yin and
• Feng Xin

Beilstein J. Nanotechnol. 2018, 9, 1770–1781, doi:10.3762/bjnano.9.168

• metal-organic frameworks (MOFs) with tunable cavities and tailorable chemistry have been demonstrated as precursors to generate TM-MCNs with various morphologies [16][17], it is still a significant challenge to prepare two-dimensional (2D) TM-MCNs derived from MOFs. TM-MCNs with 2D morphology are of

Tailoring the nanoscale morphology of HKUST-1 thin films via codeposition and seeded growth

• Landon J. Brower,
• Lauren K. Gentry,
• Amanda L. Napier and
• Mary E. Anderson

Beilstein J. Nanotechnol. 2017, 8, 2307–2314, doi:10.3762/bjnano.8.230

• -organic frameworks (MOFs), composed of both metal ions and organic ligands, represent a class of extremely porous, crystalline materials with high surface area. Research has investigated their integration as thin films, namely surface-anchored metal-organic frameworks (surMOFs), into a wide variety of

• controllable nanoscale dimensions can be designed and fabricated for integration of MOF systems directly into device architectures and sensor platforms. Keywords: atomic force microscopy; copper(II) 1,3,5-benzenetricarboxylate; ellipsometry; surface-anchored metal-organic frameworks; Introduction Metal

Experimental techniques for the characterization of carbon nanoparticles – a brief overview

• Wojciech Kempiński,
• Szymon Łoś,
• Mateusz Kempiński and
• Damian Markowski

Beilstein J. Nanotechnol. 2014, 5, 1760–1766, doi:10.3762/bjnano.5.186

• to control the charge carrier transport (“tunable electrical conductivity”) was shown in porous metal-organic frameworks (MOFs) with adsorbed guest molecules [9]. It was also shown that by appropriate choice of guest molecules, it is possible to control the charge (spin) transport in the nano

Quasi-1D physics in metal-organic frameworks: MIL-47(V) from first principles

• Danny E. P. Vanpoucke,
• Jan W. Jaeken,
• Stijn De Baerdemacker,
• Kurt Lejaeghere and
• Veronique Van Speybroeck

Beilstein J. Nanotechnol. 2014, 5, 1738–1748, doi:10.3762/bjnano.5.184

• dispersion along the the direction of the VO6 chains, similar as for other quasi-1D materials. Keywords: band structure; density functional theory (DFT); low-dimensional electronics; metal-organic frameworks (MOFs); MIL-47; Introduction Metal-organic frameworks (MOFs) present a class of materials located